Product ID:CITGO 93738, 25-086
MSDS Date:04/17/1989
FSC:9150
NIIN:00N019979
MSDS Number: CBBRW

CITGO PETROLEUM CORP

TULSA, OK 74102
US

Emergency Phone: 318-491-6215;800-424-9300(CHEMTREC)

Info Phone: 918-495-5933

Cage: 7X110

CITGO PETROLEUM CORP

3758 TULSA, OK 74102 US

Telephone: 918-495-5933

Cage: 7X110

RECLAIMING, RECYCLING OR DISPOSING OF EMPTY CNTNRS

RTECS: 9999999ZZ

SPEC PROT. AVOID PRLNGD CNTCT W/OIL. WASH

RTECS: 9999999ZZ

USE POLYMER GLOVES IF EXTENDED, DIRECT CONTACT IS

RTECS: 9999999ZZ

MANDATED STANDARDS, AS EVALUATED BY DESIGNATED

RTECS: 9999999ZZ

(ORAL,

RTECS: 9999999ZZ

Fraction By Weight: 65-80%

OSHA PEL N/K

ACGIH TLV: N/K

MINERAL OIL, PETROLEUM DISTILLATES, SOLVENT-REFINED

CAS: 64741-88-4

RTECS: PY8040501

OSHA PEL N/K

ACGIH TLV: N/K

SOLVENT REFINED RESIDUM

CAS: 64742-01-4

OSHA PEL N/K

ACGIH TLV: N/K

STODDARD SOLVENT

CAS: 8052-41-3

RTECS: WJ8925000

Fraction By Weight: <25%

OSHA PEL 500 PPM

ACGIH TLV: 100 PPM

ASHLESS DISPERSANT AND ANTI-OXIDANT (CONTAINS ING 6)

Fraction By Weight: <12%

OSHA PEL N/K

ACGIH TLV: N/K

PHOSPHORODITHOIC ACID, O-O-D1 C1-14-ALKYL ESTERS, ZINC

CAS: 68649-42-3

Fraction By Weight: <4%

OSHA PEL N/K

ACGIH TLV: N/K

(ORAL, RAT) 12.6 G/KG

Fraction By Weight: <0.1%

OSHA PEL N/K

ACGIH TLV: N/K

(100F) THERE EXISTS STILL SOME RISK OF

RTECS: 9999999ZZ

CONSIDERED. ASPIRATED MATL MAY CAUSE CHEM PNEUM OR

RTECS: 9999999ZZ

REQUIRES PROMPT SURGICAL DEBRIDEMENT. IF NOT

RTECS: 9999999ZZ

COULD INCL FLAMM OR EXPLO VAPS. CONSULT

RTECS: 9999999ZZ

LD50 LC50 Mixture:SEE INGREDIENTS
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL:LOW RISK OF INHAL. IN
ENCLSD SPACES/WHEN HOT, VAPS MAY REACH CONCS SUFFICIENT TO CAUSE
DROW, DIZZ, HDCH, NAUS OR LUNG IRRIT. MISTS ABOVE TLV MAY CAUSE
CHEM PNEUM. SKIN:MILD IRRITANT. EYES :MILDLY IRRITATING. INGEST:TOX
IS RELATIVELY LOW, HOWEVER, OF A SAYBOLT VISCOSITY OF ABOUT 185
(100F), (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:THERE EXISTS STILL SOME RISK OF ASPIR
INTO LUNGS. ON INGEST OF LG QTYS, SLIGHT GI DISCOMFORT, DIARR &
HDCH MAY OCCUR. SM DOSES MAY PRDCE IRRIT & DIARR.
INJECTION:SUBCUTANEOUS OR INTRAMUSCULAR INJECTION SHOULD BE
CONSIDERED MED EMER. CHRONIC: PRLNGD &/OR FREQUENT DERMAL CNTCT MAY
CAUSE DRYING, CRACKING (SUPDAT)
Medical Cond Aggravated by Exposure:NONE.

First Aid:INHAL: REMOVE TO FRESH AIR. RESP SUPPORT, IF NEC. SEEK MED
AID. SKIN: WASH W/SOAP & WATER. DO NOT WEAR HEAVILY CONTAMD CLTHG
BEFORE LAUNDERING. EYES: FLUSH W/LG VOLS OF WATER. SEEK MD IF ANY
COMPLICAT IONS ARISE. INGEST: DO NOT INDUCE VOMIT. SEEK MED AID.
INJECTION: SUBCUTANEOUS INJECTION IS MED EMER. SEEK MED AID IMMED.
NOTES TO MD: FOLLOWING INGEST, AT SAYBOLT VISCOSITY OF ABOUT 185
SUS, (ING 8)

Flash Point Method:PMCC
Flash Point:136F,58C
Lower Limits:1.0%
Upper Limits:6.0%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM, WATER FOG.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:WATER MAY CAUSE FROTHING.

Spill Release Procedures:REMOVE SOURCES OF HEAT OR IGNITION, PROVIDE
ADEQ VENT, CONTAIN LEAK. SMALL SPILLS: ABSORB W/SUITABLE MATL SUCH
AS RAGS, STRAW OR SAND. LARGE SPILL: CONTAIN SPILL IN EARTHEN DIKES
FOR LATER RECOVERY. R EPORT SPILLS AS REQD TO APPROP AUTHORITIES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE <150F. DO NOT APPLY HIGH
HEAT/FLAME TO CNTNR. KEEP SEPARATE FROM STRONG OXIDIZING AGENTS.
EMPTY CNTNRS MAY CNTN PROD RESIDUE WHICH (ING 11)
Other Precautions:COMBUST LIQ. CNTNS PETRO DISTILS. KEEP AWAY FROM HEAT
& FLAME. HARMFUL/FATAL IF SWALLOWED. DO NOT INDUCE VOMIT. CALL MD
IMMED. KEEP OUT OF REACH OF CHILDREN. PROT MEASURES DURING REPAIR &
MAINT OF CON TAMD EQUIP: REFER TO SECTION ON (ING 13)

Respiratory Protection:NORMALLY NONE REQUIRED. IF HIGH VAPOR OR MIST
CONCENTRATIONS EXPECTED, USE NIOSH/MSHA APPROVED RESPIRATOR FOR
ORGANIC VAPORS AND MISTS.
Ventilation:USE IN WELL VENT AREA. IN CONFINED SPACE, MECH VENT MAY BE
REQD TO KEEP LEVELS OF CERTAIN COMPONENTS BELOW (ING 15)
Protective Gloves:OIL IMPERVOUS GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
WEAR BODY-COVERING WORK CLOTHES TO AVOID PRLNGD/RPTD EXPOSURE.
Work Hygienic Practices:LAUNDER SOILED WORK CLOTHES BEFORE REUSE.
Supplemental Safety and Health
FL PT/METH: 147F,64C/COC. EFTS OF OVEREXP: (DERM) OR FOLLICULITIS.
RPTD, EXCESSIVE EXPOS TO MISTS/FUMES MAY INDUCE PULM IRRIT OR
CHRONIC BRONCH. TARGET ORGANS:LUNG, SKIN (IRRITANT), CNS
(DEPRESSANT). TOXICITY:SLIGHTLY TO MODERATELY TOX. LETHAL DOSE FOR
150 LB HUMAN ADULT MAY BE 10 TO 250 ML.

Boiling Pt:B.P. Text:>300F,>149C
Vapor Pres:<20 @ 25C
Vapor Density:>1
Spec Gravity:0.86 (H*2O=1)
Evaporation Rate & Reference:<1 (BUTYL ACETATE=1)
Solubility in Water:NEGLIGIBLE % BY WT
Appearance and Odor:BLUE/GREEN LIQUID; SLIGHT ODOR OF PETROLEUM
DISTILLATE.
Percent Volatiles by Volume:15-25

Stability Indicator/Materials to Avoid:YES
STRONG OXIDANTS.
Stability Condition to Avoid:NONE.
Hazardous Decomposition Products:CARBON DIOXIDE (CARBON MONOXIDE UNDER
INCOMPLETE COMBUSTION).

Waste Disposal Methods:IT IS THE RESPONSIBILITY OF THE USER TO
DETERMINE IF THE MATL IS A HAZ WASTE AT THE TIME OF DISPOSAL. CHECK
BEFORE DISPOSING TO BE SURE YOU ARE IN COMPLIANCE W/ALL APPLIC FED,
STATE & LOC LAWS & REGS. CHEMTREC/RCRA EMER HOTLINE #
800-424-9346.

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disclaims all liability for its use. Any person utilizing this
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particular situation.